We are unable to suggest a specific A1 Ti complex. And vibrational spectra are invariant with heat treatments of the glasses at temperatures below that at which the first crystalline phase appears, and we find no evidence therefore of structural changes associated with such heat treatments. In Chapter 7 we consider a model for the promotion of phase separation in the MgO A1(_2)O(_3) SiO(_2) system by TiO(_2), and also present evidence which suggests that the first metastable crystalline phase to form originates from the TiO(_2) rich glass phase.
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